THE SPECTROCHEMICAL PROPERTIES OF BIS(AMINO HYDROXAMATO)COPPER(II) COMPLEXES

被引：10

作者：

KURZAK, K

KURZAK, B

机构：

[1] Institute of Chemistry, Pedagogical University

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 1990年 / 46卷 / 11期

关键词：

D O I：

10.1016/0584-8539(90)80267-3

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The d-d absorption spectra of CuL2, where L = glycinehydroxamic acid (Glyha), l-α-alaninehydroxamic acid (Alaha), l-α-leucinehydroxamic acid (Leuha), l-histidinehydroxamic acid (Hisha) and sarcosinehydroxamic acid (Sarha), in aqueous solutions have been treated by the Angular Overlap Model (AOM) in C2h symmetry. Low symmetry splittings of absorption bands of the measured spectra were found by Gaussian analysis. The ligand field parameters were estimated by the Powell optimize algorithm. © 1990.

引用

页码：1561 / 1568

页数：8

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