PHOTOPHYSICAL AND PHOTOCHEMICAL PROPERTIES OF RUTHENIUM AND OSMIUM COMPLEXES WITH SUBSTITUTED TERPYRIDINES

被引：75

作者：

BELEY, M

COLLIN, JP

SAUVAGE, JP

SUGIHARA, H

HEISEL, F

MIEHE, A

机构：

[1] FAC CHIM STRASBOURG,CNRS,CHIM ORGANOMINERALE LAB,UA 422,1 RUE BLAISE PASCAL,F-67000 STRASBOURG,FRANCE

[2] UNIV LOUIS PASTEUR,23 RUE LOESS,F-67037 STRASBOURG,FRANCE

[3] CTR RECH NUCL,OPT APPL GRP,F-67037 STRASBOURG,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1991年 / 11期

关键词：

D O I：

10.1039/dt9910003157

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Ruthenium(II) and osmium(II) complexes with 2,2':6',2"-terpyridine (terpy), 4'-(p-tolyl)-2,2':6',2"-terpyridine (tterpy) and 4,4',4"-triphenyl-2,2':6',2"-terpyridine (tpterpy) have been prepared and characterized. Their electrochemical, photophysical and photochemical properties (room temperature) have been studied. Metal-to-ligand charge-transfer excited-state quenching measurements using various redox active species clearly show that [Ru(tpterpy)2]2+ is a good electron-transfer agent under light irradiation.

引用

页码：3157 / 3159

页数：3

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