A COMPARISON OF THE MOLECULAR-WEIGHTS OF POLYANILINE SAMPLES OBTAINED FROM GEL-PERMEATION CHROMATOGRAPHY AND SOLID-STATE N-15 NMR-SPECTROSCOPY

被引：71

作者：

ADAMS, PN ^{[1
]}

APPERLEY, DC ^{[1
]}

MONKMAN, AP ^{[1
]}

机构：

[1] UNIV DURHAM,DEPT PHYS,ORGAN ELECTROACT MAT GRP,DURHAM DH1 3LE,ENGLAND

来源：

POLYMER | 1993年 / 34卷 / 02期

关键词：

MOLECULAR WEIGHT; POLYANILINE; GEL PERMEATION CHROMATOGRAPHY;

D O I：

10.1016/0032-3861(93)90085-O

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Polyaniline samples of different molecular weights were prepared using aniline enriched with N-15. Molecular weights were determined by gel permeation chromatography (g.p.c.). N-15 n.m.r. spectroscopy confirmed that both samples were in the emeraldine oxidation state, and end group analysis techniques were used to compare molecular weights derived from g.p.c. with those from the n.m.r. data. In addition, the N-15 solid state n.m.r. spectra of emeraldine hydrochloride and a solvent-cast, oriented film of emeraldine base are presented.

引用

页码：328 / 332

页数：5

共 9 条

[1] OPTIMUM REACTION CONDITIONS FOR THE POLYMERIZATION OF ANILINE IN AQUEOUS-SOLUTION BY AMMONIUM PERSULFATE
ARMES, SP
MILLER, JF
[J]. SYNTHETIC METALS, 1988, 22 (04) : 385 - 393
[2] ELECTROCHEMICAL STUDY OF POLYANILINE IN AQUEOUS AND ORGANIC MEDIUM - REDOX AND KINETIC-PROPERTIES
GENIES, EM
SYED, AA
TSINTAVIS, C
[J]. MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1985, 121 (1-4): : 181 - 186
[3] Honzl J., 1968, J POLYM SCI C, V22, P451
[4] SOLUTION-STATE C-13 NUCLEAR-MAGNETIC-RESONANCE STUDIES OF POLYANILINE
KENWRIGHT, AM
FEAST, WJ
ADAMS, P
MILTON, AJ
MONKMAN, AP
SAY, BJ
[J]. POLYMER, 1992, 33 (20) : 4292 - 4298
[5] MACDIARMID AG, 1991, SCIENCE AND APPLICATIONS OF CONDUCTING POLYMERS, P117
[6] POLYANILINES - A NOVEL CLASS OF CONDUCTING POLYMERS
MACDIARMID, AG
EPSTEIN, AJ
[J]. FARADAY DISCUSSIONS, 1989, 88 : 317 - +
[7] OPTICAL AND ELECTRONIC-PROPERTIES OF STRETCH-ORIENTED SOLUTION-CAST POLYANILINE FILMS
MONKMAN, AP
ADAMS, P
[J]. SYNTHETIC METALS, 1991, 40 (01) : 87 - 96
[8] N-15 NMR OF POLYANILINE
RICHTER, AF
RAY, A
RAMANATHAN, KV
MANOHAR, SK
FURST, GT
OPELLA, SJ
MACDIARMID, AG
EPSTEIN, AJ
[J]. SYNTHETIC METALS, 1989, 29 (01) : E243 - E249
[9] 1990, GPC TRAINING COURSE

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