WITTIG REACTION OF 1-DICYANOMETHYLENEACENAPHTHEN-2-ONE

被引:13
作者
ABDOU, WM
GANOUB, NAF
机构
[1] National Research Centre, Cairo, Dokki
关键词
D O I
10.1002/hc.520030208
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The Wittig reaction of the titled compound 2 with alkoxycarbonylmethylenetriphenylphosphoranes (1a,b) has been investigated and the reaction products 6, 10, and 11 isolated and identified. On the other hand, reaction of 2 with benzoylmethylenetriphenylphosphorane (1c) proceeded only at high temperature, yielding 7c and 10. Mechanisms accounting for the formation of the adducts are discussed, and the synthetic utility of the products were tested.
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页码:133 / 137
页数:5
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