SYNTHESIS OF PHENYLBROMOTRISILANE, PHENYLIODOTRISILANE AND PHENYLHYDROTRISILANE

被引：13

作者：

HASSLER, K

KATZENBEISSER, U

机构：

[1] Institut für Anorganische Chemie der T.U., A-8010 Graz

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 421卷 / 2-3期

关键词：

D O I：

10.1016/0022-328X(91)86399-B

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The syntheses of phenylbromo- and phenyliodotrisilanes XnSi3Ph8-n (X = Br, I) are described. starting from 1.1.1.3.3.3-hexaphenyltrisilane, octaphenyltrisilane. 1-(p-Tolyl)heptaphenyltrisilane or 1.1.1-Tris(p-tolyl)pentaphenyltrisilane. A subsequent reduction with LiAlH4 gives the corresponding phenyltrisilanes HnSi3Ph8-n. All compounds were characterized with spectroscopic methods (Si-29-NMR, IR) and elemental analyses.

引用

收藏

页码：151 / 157

页数：7

相关论文

共 10 条

[1] TRIPHENYLSILYLPOTASSIUM [J].

GILMAN, H ;

WU, TC .

JOURNAL OF ORGANIC CHEMISTRY, 1953, 18 (06) :753-764

[2] SYNTHESIS AND NUCLEAR-MAGNETIC-RESONANCE OF BROMODISILANES AND IODODISILANES [J].

HASSLER, K ;

POSCHL, M .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 398 (03) :225-227

[3] SYNTHESIS AND PROPERTIES OF SOME PARA-TOLYL-PHENYL SUBSTITUTED DISILANES AND TRISILANES AND OF 1,1,1,3,3,3-HEXAPHENYLTRISILANE [J].

HASSLER, K .

MONATSHEFTE FUR CHEMIE, 1988, 119 (10) :1051-1056

[4] SYNTHESIS OF SOME PHENYLBROMODISILANES, PHENYLBROMOTRISILANES, PHENYLIODOSILANES AND PHENYLIODOTRISILANES [J].

HASSLER, K ;

POSCHL, M .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 385 (02) :201-206

[5]

HASSLER K, UNPUB

[6]

HASSLER K, 1991, SPECTROCHIM ACTA A, V7, P439

[7] KINETIC INVESTIGATIONS ON THE SILICON-ARYL CLEAVAGE WITH HBR [J].

HENGGE, E ;

EBERHARDT, H .

MONATSHEFTE FUR CHEMIE, 1979, 110 (01) :39-50

[8]

HOFLER BF, 1973, MONATSH CHEM, V104, P694

[9]

SOLLRADL H, 1982, THESIS TU GRAZ

[10] VIBRATIONAL FREQUENCIES AND THERMODYNAMIC PROPERTIES OF FLUORO-BENZENE, CHLORO-BENZENE, BROMO-BENZENE, AND IODO-BENZENE [J].

WHIFFEN, DH .

JOURNAL OF THE CHEMICAL SOCIETY, 1956, (JUN) :1350-1356