COMPOSITES FROM FURFURYL ALCOHOL AND INORGANIC SOLIDS BY CATIONIC INITIATION .3. SCANNING ELECTRON-MICROSCOPIC INVESTIGATIONS OF SOLID POLY(FURFURYL ALCOHOL)-SILICA COMPOSITES
被引:10
作者:
SPANGE, S
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机构:FRIEDRICH SCHILLER UNIV,FAC MED,DEPT ELECTRON MICROSCOPY,O-6900 JENA,GERMANY
SPANGE, S
WINKELMANN, H
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机构:FRIEDRICH SCHILLER UNIV,FAC MED,DEPT ELECTRON MICROSCOPY,O-6900 JENA,GERMANY
WINKELMANN, H
MARTINEZ, R
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h-index: 0
机构:FRIEDRICH SCHILLER UNIV,FAC MED,DEPT ELECTRON MICROSCOPY,O-6900 JENA,GERMANY
MARTINEZ, R
机构:
[1] FRIEDRICH SCHILLER UNIV,FAC MED,DEPT ELECTRON MICROSCOPY,O-6900 JENA,GERMANY
[2] UNIV HABANA,IMRE,HAVANA 10400,CUBA
来源:
ANGEWANDTE MAKROMOLEKULARE CHEMIE
|
1993年
/
208卷
关键词:
D O I:
10.1002/apmc.1993.052080112
中图分类号:
O63 [高分子化学(高聚物)];
学科分类号:
070305 ;
080501 ;
081704 ;
摘要:
Composites of poly(furfuryl alcohol) grafted onto silica, with different percentage of grafting, have been investigated by scanning electron microscopy, elemental analysis and UV/Vis-reflectance spectroscopy. The size of the silica particles used for the coating procedure is not changed till a percentage of grafting to around 30%. A content of polymer higher than 35 wt.-% enhances the bonding between the particles due to the crosslinking of poly(furfuryl alcohol) on the surface with those in solution leading to the agglomeration of the particles. A general model of cross-linked poly(furfuryl alcohol)-silica composites is suggested.