STEREOSPECIFIC SYNTHESIS AND ABSOLUTE CONFIGURATION OF (-)-DIOXODI-MU-OXO-D(-)-1,2-PROOYLENEDIAMINETETRAACETATODIMOLYBDATE(V)

被引：17

作者：

WING, RM

CALLAHAN, KP

机构：

[1] Department of Chemistry, University of California, Riverside

来源：

INORGANIC CHEMISTRY | 1969年 / 8卷 / 11期

关键词：

D O I：

10.1021/ic50081a016

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The binuclear dioxo-bridged molybdenum(V) species prevalent in 3-6 M hydrochloric acid has been placed in an optically dissymmetric environment through a stereospecific reaction with D(–)-1,2-propylenediaminetetraacetic acid. The absolute configuration of the binuclear molybdenum complex has been established. The ORD and CD spectra, richer in content than electronic spectral data previously available, are discussed. © 1969, American Chemical Society. All rights reserved.

引用

页码：2303 / &

共 30 条

[1]

ARNON DI, 1950, TRACE ELEMENTS PLANT, P31

[2] THE STEREOCHEMISTRY OF COMPLEX INORGANIC COMPOUNDS .13. A PARTIAL RESOLUTION OF RACEMIC TARTARIC ACID BY MEANS OF DIFFERENT STABILITIES OF ISOMERS OF COMPLEX IONS [J].