NATURE OF CATALYTIC EFFECT OF NI(O)- AND BF3OET2-BASED SYSTEMS IN PROPENE DIMERIZATION

被引：15

作者：

TKACH, VA ^{[1
]}

GRUZNYKH, VA ^{[1
]}

MURASHEVA, NA ^{[1
]}

MYAGMARSUREN, G ^{[1
]}

DMITRIEVA, TV ^{[1
]}

RATOVSKII, GV ^{[1
]}

ZINCHENKO, SV ^{[1
]}

SHMIDT, FK ^{[1
]}

机构：

[1] IRKUTSK STATE UNIV,IRKUTSK 664003,USSR

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 1991年 / 43卷 / 02期

关键词：

D O I：

10.1007/BF02064709

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

H-1 NMR, EPR and IR spectroscopic studies of the products of the interaction between components of the Ni[PPh3]4 + EtOH + BF3.OEt2 and Ni(PPh3)4 + BF3OEt2 systems suggest the formation of two types of complexes [HNi(PP3)3L]+BF3OEt]- and [Ni(PPh3)3L]+BF4-, which are catalytically active in propene dimerization.

引用

页码：431 / 437

页数：7