SOME ENANTIOSELECTIVE PHOTOCYCLIZATION REACTIONS IN INCLUSION CRYSTALS WITH OPTICALLY-ACTIVE HOST COMPOUNDS

被引：30

作者：

TODA, F

MIYAMOTO, H

TAKEDA, K

MATSUGAWA, R

MARUYAMA, N

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Ehime University, Matsuyama

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1993年 / 58卷 / 23期

关键词：

D O I：

10.1021/jo00075a013

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Photoirradiation of inclusion crystals of 2-[N-(2-propenyl)amino]cyclohex-2-enones, 3-oxo-2-cyclohexenecarboxamides, and 4-(3-butenyl)cyclohexa-2,5-dien-1-ones with the optically active host compound (R,R)-(-)-trans-4,5-bis(hydroxydiphenylmethyl)-1,4-dioxaspiro[4.4]nonane or (R,R)-(-)-trans-2,3-bis(hydroxydiphenylmethyl)-1,4-dioxaspiro[5.4]decane in the solid state gave optically active 9-azatricyclo[5.2.1.01,6]decan-2-ones, 2-aza-1,5-dioxospiro[3.5]nonanes, and 1-carbomethoxytricyclo[4.3.1.0(7,10)]dec-2-en-4-ones, respectively.

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页码：6208 / 6211

页数：4

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