EXTENDED HYBRID TETRATHIAFULVALENE PI-DONORS WITH OLIGOTHIENYLENEVINYLENE CONJUGATED SPACER GROUPS

被引:26
作者
ELANDALOUSSI, EH
FRERE, P
RONCALI, J
RICHOMME, P
JUBAULT, M
GORGUES, A
机构
[1] UNIV ANGERS,CNRS,EP 66,F-49045 ANGERS,FRANCE
[2] SCRMN,F-49100 ANGERS,FRANCE
关键词
D O I
10.1002/adma.19950070410
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Hybrid tetrathiafulvalenes (HTTFs) where the TTF units are linked by thienylenevinylene spacers (see Figure) are reported. It is found that the π donor properties of the materials are improved over analogues with oligothiophene spacers, and that they exhibit a smaller band gap. The evolution of the properties as a function of spacer length and the materials syntheses are discussed. (Figure Presented.) Copyright © 1995 Verlag GmbH & Co. KGaA, Weinheim
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页码:390 / 394
页数:5
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