EXPEDITIOUS SYNTHESIS OF HEPTALENE FROM NAPHTHALENE VIA A BIS-(BICYCLO[1.1.0]BUTANE) INTERMEDIATE

被引：23

作者：

PAQUETTE, LA

BROWNE, AR

CHAMOT, E

机构：

[1] Evans Chemical Laboratories. the Ohio State University, Columbus, Ohio

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 07期

关键词：

D O I：

10.1002/anie.197905461

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new expeditious entry to heptalene involves six steps starting from naphthalene via isotetralin and the polyclic hydrocarbon 1. The method capitalizes on the regiospecificity of double carbene insertion to give 1 and the ability of Ag+ to isomerize bicyclobutanes. (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

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页码：546 / 547

页数：2

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