METAL-CARBONYL CATALYZED REDUCTIVE CARBONYLATION OF SUBSTITUTED NITROBENZENES IN PRESENCE OF ALKENES AS SOLVENTS

被引：21

作者：

BASSOLI, A

RINDONE, B

TOLLARI, S

CENINI, S

CROTTI, C

机构：

[1] UNIV MILAN,DIPARTIMENTO CHIM INORGAN & MET ORGAN,I-20133 MILAN,ITALY

[2] UNIV MILAN,CTR CNR,I-20133 MILAN,ITALY

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1990年 / 60卷 / 02期

关键词：

D O I：

10.1016/0304-5102(90)85266-K

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Several nitrobenzene derivatives were submitted to reaction with carbon monoxide in alkene solvents in the presence of catalytic amounts of Ru3(CO)12. Ureas and amines were formed in this reaction, and the secondary amine derived from insertion of the nitrene intermediate at the allylic position of the alkene solvent was a secondary product. The influence of the electronic factor of the substituents on the urea vs. amine ratio is discussed. © 1990.

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页码：155 / 163

页数：9

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