2,3,7,8,12,13,17,18-OCTAMETHOXYPORPHYRIN

被引：30

作者：

MERZ, A ^{[1
]}

SCHROPP, R ^{[1
]}

LEX, J ^{[1
]}

机构：

[1] UNIV COLOGNE,INST ORGAN CHEM,W-5000 COLOGNE 41,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 02期

关键词：

D O I：

10.1002/anie.199302911

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An eightfold donor-substituted porphyrin with free meso positions 1 has been obtained for the first time. In the solid state one of the two methoxy groups on each pyrrole ring lies almost parallel to the porphyrin plane, thus allowing conjugation with the pi-electron system of the macrocycle. Further evidence is provided by the spectroscopic properties of 1, which deviate significantly from those of the related octaalkylporphyrins.

引用

页码：291 / 293

页数：3

共 17 条

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