OPTIMAL-CONTROL OF IBR CURVE-CROSSING REACTIONS

被引：20

作者：

GROSS, P

BAIRAGI, DB

MISHRA, MK

RABITZ, H

机构：

[1] INDIAN INST TECHNOL,DEPT CHEM,POWAI 400067,INDIA

[2] PRINCETON UNIV,DEPT CHEM,PRINCETON,NJ 08544

来源：

CHEMICAL PHYSICS LETTERS | 1994年 / 223卷 / 03期

关键词：

D O I：

10.1016/0009-2614(94)00447-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Control of IBr photodissociation branching ratios is explored using optimal control theory to design the requisite pulses which produce ground or spin-orbit excited bromine atoms. To conform to experimental pulse shaping limitations, these pulses are confined to a limited bandwidth and further modified by inspection of the power spectra from which extraneous frequency components are removed. Branching ratios using the filtered fields are shown to still provide appreciable selectivity, but with the added benefit of more feasible pulse shapes.

引用

页码：263 / 268

页数：6

共 22 条

[1] POPULATION-INVERSION IN A MULTILEVEL SYSTEM - A MODEL STUDY [J].