PREPARATION OF [FE(C5H5)(DPPE)(NCCH3)]BR AND ITS CONVERSION TO SEVERAL FE(C5H5)(DPPE)X COMPOUNDS

被引：61

作者：

TREICHEL, PM

MOLZAHN, DC

机构：

[1] Department of Chemistry, University of Wisconsin, Madison

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1979年 / 9卷 / 01期

关键词：

D O I：

10.1080/00945717908057448

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The compound [Fe(C5H5)(dppe)(NCCH3)]Br is conveniently prepared by irradiation of Fe(C5H5)(CO)2Br and dppe (dppe = 1,2-bis(diphenylphosphino)ethane) in acetonitrile. The acetonitrile ligand is easily displaced by anionic ligands (X- = CN-, SCN-, SPh-, I-, Br-, CH3- (as CH3MgI) and H- (as LiAlH4)) to give the complexes Fe(C5H5)(dppe)X. © 1979, Taylor & Francis Group, LLC. All rights reserved.

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页码：21 / 29

页数：9

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