REARRANGEMENT OF ALLYLIC AND PROPARGYLIC ALCOHOLS CATALYZED BY THE COMBINED USE OF TETRABUTYLAMMONIUM PERRHENATE(VII) AND PARA-TOLUENESULFONIC ACID

被引：58

作者：

NARASAKA, K

KUSAMA, H

HAYASHI, Y

机构：

来源：

CHEMISTRY LETTERS | 1991年 / 08期

关键词：

D O I：

10.1246/cl.1991.1413

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Allylic rearrangement and/or dehydration of allylic alcohols proceed by the use of a catalytic amount of tetrabutylammonium perrhenate and p-toluenesulfonic acid. Treatment of propargylic alcohols with the above reagents affords the rearranged products, alpha,beta-unsaturated carbonyl compounds.

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页码：1413 / 1416

页数：4

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