PREPARATION AND PROPERTIES OF VANADYL(IV) SACCHARINATE

被引：41

作者：

FERRER, EG

ETCHEVERRY, SB

BARAN, EJ

机构：

来源：

MONATSHEFTE FUR CHEMIE | 1993年 / 124卷 / 04期

关键词：

VANADYL(IV) SACCHARINATE; IR SPECTRA; ELECTRONIC SPECTRA; MAGNETIC AND THERMAL BEHAVIOR;

D O I：

10.1007/BF00814132

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of a new vanadyl(IV)/saccharin complex is reported. Its bonding characteristics differ considerably from all known divalent metal-saccharinates. In this complex a VO(OH)+ moiety is coordinated to a saccharin molecule through its carbonyl oxygen and to a saccharinate ion through its deprotonated nitrogen. Two water molecules complete the coordination sphere. X-ray powder diagrams, infrared- and electronic absorption-spectra were recorded and analyzed for the characterization of the compound and its coordination properties. Besides, the magnetic susceptibility and the thermal behaviour were also investigated.

引用

页码：355 / 366

页数：12

共 38 条

[1] THE PREPARATION AND X-RAY CRYSTAL-STRUCTURE OF A SACCHARIN COMPLEX OF COPPER(II) [J].