STABLE COORDINATION-COMPOUNDS OF THIAZYL FLUORIDE - STRUCTURE OF [CO(NSF)6]2+ IN THE CRYSTAL

被引：20

作者：

BUSS, B ^{[1
]}

JONES, PG ^{[1
]}

MEWS, R ^{[1
]}

NOLTEMEYER, M ^{[1
]}

SHELDRICK, GM ^{[1
]}

机构：

[1] UNIV GOTTINGEN,INST ANORGAN,D-3400 GOTTINGEN,FED REP GER

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 03期

关键词：

D O I：

10.1002/anie.197902311

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

“Thiazyl fluoride” (NSF), the simplest nitrogen‐sulfur‐fluorine compound, is unstable at room temperature. It has now been stabilized as [Co(NSF)6][AsF6]2. The pronounced shortening of the SF and the SN bonds on complexation is worthy of note. (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：231 / 231

页数：1

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