Electroactive polymers possessing crown ether sites. Anodic polymerization of dinaphtho-18-crown-6 compared with the anodic behaviour of 2,3-dialkoxynaphthalenes

被引：11

作者：

Simonet, J

Patillon, H

Belloncle, C

SimonetGueguen, N

Cauliez, P

机构：

[1] Laboratoire d'Electrochimie Associé au CNRS, Université de Rennes I, Beaulieu

来源：

SYNTHETIC METALS | 1995年 / 75卷 / 02期

关键词：

crown ether; polymerization; dimerization; naphthalene; anodic oxidation;

D O I：

10.1016/0379-6779(95)03397-3

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Dinaphtho-18-crown-6 exhibits capability to be anodically polymerized. A polymer structure formed in this way is proposed and could correspond to linkage of naphthalene moieties with parts of the chain corresponding to an electronic conducting polymer and others to a redox-type polymer. Moreover, arguments concerning anodic bonding between naphthalene groups (formation and characterization of dimers for low current consumption) are developed by taking into account some 2,3-dialkoxynaphthalenes and relevant crown ethers oxidized under similar experimental conditions.

引用

页码：103 / 110

页数：8

共 17 条

[1] THE ANODIC TRIMERIZATION OF AROMATIC ORTHODIETHERS - NEW DEVELOPMENTS [J].