STRUCTURE OF COBALT(II) ACETATE AND COBALT(III) ACETATE IN ACETIC-ACID SOLUTION

被引：37

作者：

HENDRIKS, CF ^{[1
]}

VANBEEK, HCA ^{[1
]}

HEERTJES, PM ^{[1
]}

机构：

[1] DELFT UNIV TECHNOL,CHEM TECHNOL LAB,DELFT,NETHERLANDS

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY PRODUCT RESEARCH AND DEVELOPMENT | 1979年 / 18卷 / 01期

关键词：

D O I：

10.1021/i360069a009

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Optical and ion migration experiments were carried out with acetic acid solutions of CoII and CoII acetate. The results indicate a mononuclear structure with six ligands. The largest amount of these complexes is uncharged. It is proposed that in anhydrous acetic acid CoII acetate can be represented as Co” (OAc″)2 (HOAc)4 and Co″1 acetate as Co1” (OAc″)3 (HOAc)3. Addition of water, (ring substituted) benzaldehyde, benzoic acid, or phenol results in exchange reactions with acetic acid ligands. © 1979, American Chemical Society. All rights reserved.

引用

页码：43 / 46

页数：4

共 11 条

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