KINETICS OF CONDENSATION POLYMERIZATION

被引：50

作者：

SECOR, RM

机构：

[1] E. I. du Pont de Nemours & Company, Inc., Wilmington, Delaware

来源：

AICHE JOURNAL | 1969年 / 15卷 / 06期

关键词：

D O I：

10.1002/aic.690150612

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The final stages of condensation polymerization are characterized by a rapid rise in molecular weight, as the condensation product is formed and diffuses out of the polymer. The process occurring is one of desorption accompanied by a chemical reaction. The penetration theory equations for a generalized condensation polymerization reaction have been solved and some solutions are presented. The penetration theory solution, obtained by finite‐difference computations, is compared with an analytical solution for the special case of no diffusional resistance. Copyright © 1969 American Institute of Chemical Engineers

引用

页码：861 / &