SPIN-FORBIDDEN DISSOCIATION-RECOMBINATION REACTION SO3-REVERSIBLESO2+O

被引：30

作者：

ASTHOLZ, DC

GLANZER, K

TROE, J

机构：

[1] Institut für Physikalische Chemie der Universität, D-3400 Göttingen

来源：

JOURNAL OF CHEMICAL PHYSICS | 1979年 / 70卷 / 05期

关键词：

D O I：

10.1063/1.437751

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Rate constants for the spin-forbidden dissociation process SO3 + Ar→SO2 + O + Ar have been measured in shock waves between 1700 and 2500 K. The results are compared with data on the low temperature (200-400 K) recombination reaction. The analysis in terms of unimolecular reaction rate theory allows for a determination of the threshold energy of the reaction. © 1979 American Institute of Physics.

引用

页码：2409 / 2413

页数：5

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