ASSIGNMENT OF PROTON AND C-13 SPECTRA OF A SUCROSE ESTER FROM TOBACCO BY INVERSE DETECTED 2-DIMENSIONAL HETERONUCLEAR CORRELATED NMR-SPECTROSCOPY

被引：6

作者：

HIMMELSBACH, DS ^{[1
]}

VANHALBEEK, H ^{[1
]}

ARRENDALE, RF ^{[1
]}

SEVERSON, RF ^{[1
]}

机构：

[1] UNIV GEORGIA,COMPLEX CARBOHYDRATE RES CTR,ATHENS,GA 30602

来源：

MAGNETIC RESONANCE IN CHEMISTRY | 1990年 / 28卷 / 08期

关键词：

Heteronuclear [!sup]1[!/sup]H–[!sup]13[!/sup]C Chemical shift correlation; Inverse detected 2D NMR; Multiple quantum 2D NMR; Sucrose ester; Tobacco;

D O I：

10.1002/mrc.1260280805

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complete assignment of the proton and carbon chemical shifts of 6‐O‐acetyl‐2,3,4‐tri‐O‐(3S‐methylpentanoyl)‐α‐D‐glucopyranosyl‐β‐D‐fructofuranoside, a naturally occurring flavor precursor of tobacco, is presented. These assignments were made by comparison of the spectra obtained from 1H‐detected heteronuclear multiple quantum coherence and 1H‐detected heteronuclear multiple‐bond connectivity two‐dimensional NMR experiments. Copyright © 1990 John Wiley & Sons, Ltd.

引用

页码：682 / 687

页数：6

共 18 条

[1] CHARACTERIZATION OF THE SUCROSE ESTER FRACTION FROM NICOTIANA-GLUTINOSA [J].

ARRENDALE, RF ;

SEVERSON, RF ;

SISSON, VA ;

COSTELLO, CE ;

LEARY, JA ;

HIMMELSBACH, DS ;

VANHALBEEK, H .

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1990, 38 (01) :75-85

[2] DETERMINATION OF HETERONUCLEAR COUPLING-CONSTANTS VIA SEMISELECTIVE TWO-DIMENSIONAL J-SPECTROSCOPY [J].

BAX, A .

JOURNAL OF MAGNETIC RESONANCE, 1983, 52 (02) :330-334

[3] H-1 AND C-13 ASSIGNMENTS FROM SENSITIVITY-ENHANCED DETECTION OF HETERONUCLEAR MULTIPLE-BOND CONNECTIVITY BY 2D MULTIPLE QUANTUM NMR [J].

BAX, A ;

SUMMERS, MF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (08) :2093-2094

[4] SENSITIVITY-ENHANCED TWO-DIMENSIONAL HETERONUCLEAR SHIFT CORRELATION NMR-SPECTROSCOPY [J].

BAX, A ;

SUBRAMANIAN, S .

JOURNAL OF MAGNETIC RESONANCE, 1986, 67 (03) :565-569

[5]

CHUMAN T, 1977, AGR BIOL CHEM TOKYO, V41, P1020

[6] DISTORTIONLESS ENHANCEMENT OF NMR SIGNALS BY POLARIZATION TRANSFER [J].

DODDRELL, DM ;

PEGG, DT ;

BENDALL, MR .

JOURNAL OF MAGNETIC RESONANCE, 1982, 48 (02) :323-327

[7] PARTIALLY ESTERIFIED SUCROSE DERIVATIVES - SYNTHESIS OF 6-O-ACETYL-2,3,4-TRI-O-[(S)-3-METHYLPENTANOYL]SUCROSE, A NATURALLY-OCCURRING FLAVOR PRECURSOR OF TOBACCO [J].

GAREGG, PJ ;

OSCARSON, S ;

RITZEN, H .

CARBOHYDRATE RESEARCH, 1988, 181 :89-96

[8]

KALLIANOS A G, 1976, RECENT ADV TOBACCO S, p61

[9] ASSIGNMENT OF CARBONYL CARBONS AND SEQUENCE-ANALYSIS IN PEPTIDES BY HETERONUCLEAR SHIFT CORRELATION VIA SMALL COUPLING-CONSTANTS WITH BROAD-BAND DECOUPLING IN T1 (COLOC) [J].

KESSLER, H ;

GRIESINGER, C ;

ZARBOCK, J ;

LOOSLI, HR .

JOURNAL OF MAGNETIC RESONANCE, 1984, 57 (02) :331-336

[10]

MATSUSHIMA S, 1979, BEITR TABAKFORSCH, V10, P31

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