A CYCLOBUTANONE-BASED TANDEM FREE-RADICAL REARRANGEMENT

被引:5
作者
DOWD, P
ZHANG, W
MAHMOOD, K
机构
[1] Department of Chemistry University of Pittsburgh, Pittsburgh
基金
美国国家卫生研究院;
关键词
D O I
10.1016/S0040-4039(00)77247-9
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Free radical reaction of endo-haroalkylbicyclo[4.2.0]oct-2-en-7-ones 1 and 11 leads to sequential rearrangement and formation of the novel, bridged tricyclic ketones 2 and 13. A mechanism for this unusual transformation is proposed.
引用
收藏
页码:5563 / 5566
页数:4
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