STABLE CARBOCATIONS .206. ONSET OF SIGMA-DELOCALIZATION IN SUBSTITUTED 2-PHENYL-2-NORBORNYL CATIONS AS STUDIES BY C-13 NUCLEAR MAGNETIC-RESONANCE SPECTROSCOPY - APPLICATION OF TOOL-OF-INCREASING-ELECTRON-DEMAND TO 2-NORBORNYL SYSTEM

被引：69

作者：

OLAH, GA ^{[1
]}

PRAKASH, GKS ^{[1
]}

LIANG, G ^{[1
]}

机构：

[1] CASE WESTERN RESERVE UNIV,DEPT CHEM,CLEVELAND,OH 44106

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1977年 / 99卷 / 17期

关键词：

D O I：

10.1021/ja00459a026

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：5683 / 5687

页数：5

共 34 条

[1]

[Anonymous], COMMUNICATION

[2]

BATTISTE MA, 1975, TETRAHEDRON LETT, V14, P1255

[3]

BINGHAM RC, 1975, J AM CHEM SOC, V97, P1291

[4] SOLVOLYSIS OF 9-ARYL-9-PENTACYCLO[4.3.0.02,4.03,8.05,7]-NONYL PARA-NITROBENZOATES - UNAMBIGUOUS EVIDENCE FOR PRESENCE OF CARBON PARTICIPATION BY APPLICATION OF TOOL OF INCREASING ELECTRON DEMAND [J].

BROWN, HC ;

RAVINDRANATHAN, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (01) :299-300

[5] SOLVOLYSIS OF 2-[3,5-BIS(TRIFLUOROMETHYL)PHENYL]-2-NORBORNYL P-NITROBENZOATES AND 1-ARYLCYCLOPENTYL P-NITROBENZOATES - FAILURE OF A FURTHER INCREASE IN ELECTRON DEMAND TO ALTER EXO-ENDO RATE RATIO [J].

BROWN, HC ;

RAVINDRANATHAN, M ;

TAKEUCHI, KI ;

PETERS, EN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (10) :2899-2900

[6] QUESTION OF SIGMA-BRIDGING IN SOLVOLYSIS OF 2-NORBORNYL DERIVATIVES [J].

BROWN, HC .

ACCOUNTS OF CHEMICAL RESEARCH, 1973, 6 (11) :377-386

[7] EXPLORATIONS IN NONCLASSICAL ION AREA [J].

BROWN, HC .

TETRAHEDRON, 1976, 32 (02) :179-204

[8] RATES AND PRODUCTS OF SOLVOLYSIS OF 2-METHYL-2-NORBORNENYL AND 2,5-DIMETHYL-2-NORBORNENYL P-NITROBENZOATES - EVIDENCE FOR INCREASING PI-PARTICIPATION WITH INCREASING ELECTRON DEMAND [J].

BROWN, HC ;

PETERS, EN ;

RAVINDRANATHAN, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (10) :2900-2902

[9] COMPARISON OF EFFECT OF SUBSTITUENTS AT 2-POSITION OF NORBORNYL SYSTEM WITH THEIR EFFECT IN REPRESENTATIVE SECONDARY ALIPHATIC + ALICYCLIC DERIVATIVES . EVIDENCE FOR ABSENCE OF NONCLASSICAL STABILIZATION OF NORBORNYL CATION [J].

BROWN, HC ;

REI, MH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1964, 86 (22) :5008-&

[10] NONCLASSICAL ION PROBLEM [J].

BROWN, HC .

CHEMICAL & ENGINEERING NEWS, 1967, 45 (07) :86-&

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