TRANSITION-METAL COMPLEXES WITH THE TETRATHIOSQUARATE DIANION AS BRIDGING BISCHELATE LIGAND

被引：34

作者：

GOTZFRIED, F ^{[1
]}

BECK, W ^{[1
]}

LERF, A ^{[1
]}

SEBALD, A ^{[1
]}

机构：

[1] INST TIEFTEMPERATURFORSCH,D-8046 GARCHING,FED REP GER

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 06期

关键词：

D O I：

10.1002/anie.197904631

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Organometallic compounds having a chain‐type structure such as 1 are of interest as potential one‐dimensional electrical conductors. An example of 1 is Ni25(C4S4)26K2·x H2O (x ≈ 8); the conductivity of the compressed powder at 20 °C is 5 × 10−4 Ω−1 cm−1. The monomeric complex 2 can be reduced irreversibly in two steps by voltammetry. (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：463 / 464

页数：2

共 18 条

[1] POLYCARBONYLS .16. SYNTHESIS AND STRUCTURE OF SULFUR ANALOG OF SQUARIC ACID DIANION K2[C4S4)-H2O
ALLMANN, R
DEBAERDEMAEKER, T
MANN, K
MATUSCH, R
SCHMIEDEL, R
SEITZ, G
[J]. CHEMISCHE BERICHTE-RECUEIL, 1976, 109 (06): : 2208 - 2215
[2] REACTIONS OF METAL-COMPLEXES WITH STRAINED RINGS .8. REACTIONS OF A SQUARIC ACID WITH TRIPHENYLPHOSPHINE PLATINUM (O) COMPOUNDS
BECK, W
GOETZFRIED, F
CHEN, MW
[J]. CHEMISCHE BERICHTE-RECUEIL, 1978, 111 (11): : 3719 - 3725
[3] METAL DITHIOSQUARATES .2. SYNTHESIS AND CHARACTERIZATION OF BIS(DITHIOSQUARATO) TETRAHEDRAL AND PLANAR COMPLEXES - CRYSTAL AND MOLECULAR-STRUCTURE OF POTASSIUM BIS(DITHIOSQUARATO)NICKELATE(II) DIHYDRATE
COUCOUVANIS, D
HOLAH, DG
HOLLANDER, FJ
[J]. INORGANIC CHEMISTRY, 1975, 14 (11) : 2657 - 2665
[4] X-RAY, SPECTROSCOPIC, AND MAGNETIC STUDY OF STRUCTURE OF NICKEL SQUARATE DIHYDRATE, NIC4O4 . 2H2O
HABENSCHUSS, M
GERSTEIN, BC
[J]. JOURNAL OF CHEMICAL PHYSICS, 1974, 61 (03) : 852 - 860
[5] DERIVATE DES MANGANCARBONYLS MIT SCHWEFELORGANISCHEN LIGANDEN
HIEBER, W
GSCHEIDM.M
[J]. CHEMISCHE BERICHTE-RECUEIL, 1966, 99 (07): : 2312 - &
[6] SYNTHESIS AND PROPERTIES OF O-ALKYLXANTHOGENATOCARBONYL COMPLEXES OF MANGANESE(I) AND RHENIUM(I)
LAUFEN, H
MEYN, B
STEINHAUSER, KG
VOGEL, D
KRAMOLOWSKY, R
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1976, 112 (02) : C34 - C38
[7] DITHIOCARBOXYLATE COMPLEXES OF MANGANESE AND RHENIUM
LINDNER, E
GRIMMER, R
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1970, 25 (02) : 493 - &
[8] MOSSBAUER, MAGNETIC, AND ELECTRONIC STRUCTURAL STUDY OF 2 IRON SQUARATE COMPLEXES
LONG, GJ
[J]. INORGANIC CHEMISTRY, 1978, 17 (10) : 2702 - 2707
[9] Miller J. S., 1976, PROG INORG CHEM, V20, P1
[10] NEW AROMATIC ANIONS .9. ANION RADICALS OF MONOCYCLIC OXOCARBONS
PATTON, EV
WEST, R
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1973, 77 (22) : 2652 - 2654

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