EVIDENCES ABOUT THE STEREOCHEMISTRY OF 14-HYDROXY-9-EPI-BETA-CARYOPHYLLENE

被引：11

作者：

BARRERO, AF

OLTRA, JE

BARRAGAN, A

机构：

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 28期

关键词：

D O I：

10.1016/S0040-4039(00)94502-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

From natural 14-hydroxy-9-epi-β-caryophyllene (1), the acyl derivatives 2 and 3 were prepared. These compounds appeared as a mixture of two conformational isomers (7/3). When 1 was oxidized with MCPBA, epoxides 7 and 9 were obtained. The rigid conformation of 7 and 9 allowed us to establish their skeleton and cis interannular junction. Thus, the proposed structure for 1 was confirmed. © 1990.

引用

页码：4069 / 4072

页数：4

共 5 条

[1] 4 TERPENOIDS FROM CEDRUS-LIBANOTICA [J].