FREE-RADICAL CYCLIZATIONS OF TERMINAL ALKYNES WITH OXIME ETHERS

被引：58

作者：

ENHOLM, EJ

BURROFF, JA

JARAMILLO, LM

机构：

[1] Department of Chemistry, University of Florida, Gainesville

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 26期

关键词：

D O I：

10.1016/S0040-4039(00)97455-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A benzyl oxime ether tethered to a terminal alkyne efficiently undergoes a free radical hydrostannylation reaction to afford five- and six-membered rings bearing a protected amine and a vinyl stannane functionality. These products were subsequently protiodestannylated to obtain the unsubstituted exo-methylene compounds. © 1990.

引用

页码：3727 / 3730

页数：4

共 15 条

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