REACTION OF DIMETHYLZIRCONOCENE WITH ALKYLMAGNESIUM HALIDES AS A POTENTIALLY GENERAL-METHOD FOR PREPARING ZIRCONOCENE-ALKENE COMPLEXES

被引：49

作者：

TAKAHASHI, T ^{[1
]}

NITTO, Y ^{[1
]}

SEKI, T ^{[1
]}

SABURI, M ^{[1
]}

NEGISHI, E ^{[1
]}

机构：

[1] PURDUE UNIV, DEPT CHEM, W LAFAYETTE, IN 47907 USA

来源：

CHEMISTRY LETTERS | 1990年 / 12期

关键词：

D O I：

10.1246/cl.1990.2259

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Addition of one equivalent of RCH2CH2MgX to Cp2ZrMe2 (Cp = C5H5) in the presence of PMe3 led to a transmetalation reaction to afford zirconocene-alkene complexes Cp2Zr(RCH=CH2)(PMe3) in good yields along with the formation of MeMgX.

引用

页码：2259 / 2262

页数：4

共 13 条

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