FIXATION AND REDUCTION OF DINITROGEN BY VANADIUM(II) AND VANADIUM(III) - SYNTHESIS AND STRUCTURE OF DINITROGENMESITYLVANADIUM COMPLEXES

被引：49

作者：

FERGUSON, R

SOLARI, E

FLORIANI, C

CHIESIVILLA, A

RIZZOLI, C

机构：

[1] UNIV LAUSANNE,CHIM SECT,PL CHATEAU 3,CH-1005 LAUSANNE,SWITZERLAND

[2] UNIV PARMA,CNR,CTR STUDIO STRUTTURIST DIFFRATTOMETRICA,IST STRUTTURIST CHIM,I-43100 PARMA,ITALY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 03期

关键词：

D O I：

10.1002/anie.199303961

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two short V-N bonds and a long N-N bond, as hat is situated in the cavity created by the VNNV unit and two mesityl (mes) ligands are the intriguing characteristics of the anion of complex 1. It is formed by the reduction of [V(mes)3(thf)] with Na under N2 and on protonation yields NH3 and N2H4. Two mes ligands at both V and V' are omitted from the picture shown on the right.

引用

页码：396 / 397

页数：2

共 26 条

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