TUNING THE BANDGAP FOR POLYMERIC SMART WINDOWS AND DISPLAYS

被引：59

作者：

GUSTAFSSONCARLBERG, JC

INGANAS, O

ANDERSSON, MR

BOOTH, C

AZENS, A

GRANQVIST, CG

机构：

[1] CHALMERS UNIV TECHNOL,DEPT ORGAN CHEM & POLYMER TECHNOL,S-41296 GOTHENBURG,SWEDEN

[2] UNIV MANCHESTER,MANCHESTER POLYMER CTR,MANCHESTER M13 9PL,LANCS,ENGLAND

[3] TEKNIKUM UNIV UPPSALA,S-75105 UPPSALA,SWEDEN

来源：

ELECTROCHIMICA ACTA | 1995年 / 40卷 / 13-14期

关键词：

ELECTROCHROMISM; CONJUGATED POLYMER; POLYMER ELECTROLYTE; OPTICAL SPECTROSCOPY; SUBSTITUTED POLYTHIOPHENE;

D O I：

10.1016/0013-4686(95)00169-F

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The band gap, and thus the optical properties, of polythiophene can be turned for use in electrochromic applications by attaching substituents to the monomers before polymerization. Electron donating substituents lower the bandgap, while steric interaction of side groups on adjacent thiophene rings forces the conjugated backbone to twist and increases the band gap. By choosing the right combination, a polymer with specific optical properties can be designed. Properties of interest for electrochromic applications, like oxidation potential, ionic conductivity and thermal stability, can also be improved by substitution. Poly(ethylene-dioxythiophene) (PEDOT) has shown to have interesting optical properties, increased ionic conductivity and a high thermal stability.

引用

页码：2233 / 2235

页数：3

共 24 条

[1] SYNTHESIS OF SOLUBLE POLY(ALKYLTHIOPHENES) WHICH ARE THERMALLY STABLE IN THE DOPED STATE [J].