AN OXOVANADIUM(IV) COMPLEX CHELATED BY DIPYRIDYL SULFIDE

被引：10

作者：

KONDO, M ^{[1
]}

KAWATA, S ^{[1
]}

KITAGAWA, S ^{[1
]}

KISO, H ^{[1
]}

MUNAKATA, M ^{[1
]}

机构：

[1] KINKI UNIV,DEPT CHEM,OSAKA,OSAKA 577,JAPAN

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1995年 / 51卷

关键词：

D O I：

10.1107/S0108270194008127

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complex (di-2-pyridyl sulfide-N,N')dichlorooxovanadium(IV), [VOCl2(C10H8N2S)], was prepared by the reaction of VCl3 and sodium 2-mercaptopyridine N-oxide in ethanol solution under an atmosphere of argon. The N atoms of the dipyridyl sulfide ligand and the two chloride ligands coordinate to the oxovanadium(IV) ion, to give a complex with square-pyramidal geometry. The dipyridyl sulfide ligand forms a folded six-membered chelate ring with a larger N-V-N bite angle than that formed by 2,2'-bipyridyl.

引用

页码：567 / 569

页数：3