SYNTHESIS AND MOLTEN-STATE POLYMERIZATION OF SOME NOVEL CONJUGATED DIACETYLENES

被引：15

作者：

FOMINA, L ^{[1
]}

ALLIER, H ^{[1
]}

FOMINE, S ^{[1
]}

SALCEDO, R ^{[1
]}

OGAWA, T ^{[1
]}

机构：

[1] NATL AUTONOMOUS UNIV MEXICO,INST INVEST MAT,MEXICO CITY 04510,DF,MEXICO

来源：

POLYMER JOURNAL | 1995年 / 27卷 / 06期

关键词：

DIACETYLENE; AMORPHOUS POLYDIACETYLENES; WITTIG REACTION; AROMATIC ACETYLENES;

D O I：

10.1295/polymj.27.591

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A series of new, highly conjugated diacetylenes, 4-ethynylstilbene derivatives, were synthesized and their polymerization was studied. None of them was found to undergo topochemical polymerization in the solid state but they readily polymerized in the molten state to give red transparent and amorphous polymers. All the polymers had an absorption maximum in the visible spectra around 500 nm, and FT-IR data showed the enyne structure of the polymer chain resulted from 1,4-addition.

引用

页码：591 / 600

页数：10

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