In this paper, the pseudobinary system CH3COONa . 3H2O-CO(NH2)2 is studied by means of differential scanning calorimetry (DSC). Its eutectic mixture is found to melt congruently at 30-degrees-C, its heat of fusion is 200.5 J/g, considering the temperature of phase change and its heat storage capacity. This eutectic mixture is an excellent material for latent heat storage of solar energy.