2,7-DIMETHYLTRICYCLO[4.3.1.1(3,8)]UNDECANE-SYN-2,SYN-7-DIOL AS A HOST FOR VOLATILE AND ODOROUS GUEST MOLECULES

被引：5

作者：

BISHOP, R

CRAIG, DC

MAROUGKAS, A

SCUDDER, ML

机构：

[1] School of Chemistry, The University of New South Wales, Sydney

来源：

TETRAHEDRON | 1994年 / 50卷 / 29期

关键词：

D O I：

10.1016/S0040-4020(01)85348-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The title compound 1 forms two different classes of lattice inclusion compound: helical tubulates where the guests are contained in parallel canals, and ellipsoidal clathrates with each guest enclosed in a discrete cavity. Formation of these lattice types can be predicted since they are dependent on the size and shape of the guest molecule. This paper presents a preliminary investigation on the ability of 1 to act as a host for low boiling or odorous guests. The preparation and crystal structure of the helical tubulate (1)(3).(CBr2F2) and the ellipsoidal clathrate (1)(4).(CS2) are described. Since the cavity of the ellipsoidal clathrate class is a cage formed by two interpenetrating sublattices this family of inclusion compounds has considerable potential as a chemical storage system.

引用

页码：8749 / 8756

页数：8

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