LINEAR-CHAIN COMPOUNDS OF MOLYBDENUM(II) ACETATE LINKED BY PYRAZINE, 4,4'-BIPYRIDINE, AND 1,4-DIAZABICYCLO[2.2.2]OCTANE

被引：27

作者：

HANDA, M ^{[1
]}

MIKURIYA, M ^{[1
]}

KOTERA, T ^{[1
]}

YAMADA, K ^{[1
]}

NAKAO, T ^{[1
]}

MATSUMOTO, H ^{[1
]}

KASUGA, K ^{[1
]}

机构：

[1] KWANSEI GAKUIN UNIV, SCH SCI, DEPT CHEM, NISHINOMIYA, HYOGO 662, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1995年 / 68卷 / 09期

关键词：

D O I：

10.1246/bcsj.68.2567

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of linear-chain complexes of molybdenum(II) acetate linked by bidentate bridging ligands, [Mo-2(O2CCH3)(4)L](n) (L=pyrazine (pyz), 4,4'-bipyridine (4,4'-bpy), and 1,4-diazabicyclo[2.2,2]octane (dabco)), have been prepared, and their crystal structures determined by an X-ray diffraction method. It has been shown that the relatively weak coordinations of the bridging ligands at the axial positions of Mo-2(O2CCH3)4 (Mo-N=2.619 (8)-2.658(6) Angstrom) can effectively control the arrangement of the dimer units to give chain structures with good linearities. No significant interactions between the dimer units have been observed.

引用

页码：2567 / 2572

页数：6

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