THIIRANIUM IONS AS REACTION INTERMEDIATES

被引：135

作者：

MUELLER, WH

机构：

[1] Central Basic Research Laboratory, Esso Research and Engineering Co., Linden, New Jersey

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1969年 / 8卷 / 07期

关键词：

Sulfenyl chlorides; Sulfur; Thiiranium ions;

D O I：

10.1002/anie.196904821

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The addition of sulfenvl chlorides or sulfur dichloride to unsaturated compounds proceeds via thiiranium ions. The present article reviews the electronic and steric factors influencing the nature of these ions and their effects on subsequent ring opening and product formation. For the purpose of this discussion results primarily from electrophilic ring opening have been chosen to illustrate these factors. Solvent and temperature effects have been disregarded. Copyright © 1969 by Verlag Chemie, GmbH, Germany

引用

页码：482 / &

共 93 条

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