CLEAVAGE OF ALPHA-NITRO KETONES

被引：12

作者：

FEUER, H

PIVAWER, PM

机构：

[1] Department of Chemistry, Purdue University, Lafayette

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1969年 / 34卷 / 10期

关键词：

D O I：

10.1021/jo01262a025

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The cleavage of α-nitro ketones has been recently the subject of several investigations.2-7 In a previous publication we noted that in refluxing methanolic acetic acid 2-nitrocyclohexanone (1) and 2-nitro-3,5,5-trimethyl cyclopentanone (2) were converted into methyl 6-nitrohexanoate (3) and methyl 2,2,4-trimethyl-5-nitropentanoate, respectively, while under similar conditions 2-nitrocycloheptanone (4) and 2-nitrocyclooctanone failed to react. © 1969, American Chemical Society. All rights reserved.

引用

页码：2917 / &

共 11 条

[1]

CLAISEN L, 1896, CHEM BER, V29, P1007

[2]

ENSER GR, 1956, J CHEM SOC, P4068

[3] ALKYL NITRATION OF ACTIVE METHYLENE COMPUNDS .4. MONONITRATION OF KETONES [J].