ELECTRON SPIN RESONANCE SPECTRA OF OXYVANADIUM(V) IONS IN OXIDATION-REDUCTION SYSTEMS

被引:22
作者
BAINS, MS
ARTHUR, JC
HINOJOSA, O
机构
[1] Southern Regional Research Laboratory, New Orleans
关键词
D O I
10.1021/ja01045a012
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Interaction of free radicals, formed in Ce4+-H2O2 and Fe2+-H2O2 solutions, with oxyvanadium(V) ions generated an eight-line esr spectrum when recorded at low modulation amplitude. When recorded at high modulation amplitude, a doublet-like esr spectrum was obtained. The oxyvanadium(V)-free-radical complex in the Ce4+-H2O2 system at 22° decayed with k = -6.2 sec−1 and t1/2 = 0.1 sec. © 1969, American Chemical Society. All rights reserved.
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页码:4673 / &
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