SYNTHESIS AND REACTIVITY OF THE FORMALLY UNSATURATED DIRUTHENIUM DIPHOSPHAZANE-BRIDGED SPECIES [RU2(CO)4(MU-(RO)2PN(ET)P(OR)2)2] (R = ME OR PRI)

被引：20

作者：

FIELD, JS ^{[1
]}

HAINES, RJ ^{[1
]}

SUNDERMEYER, J ^{[1
]}

WOOLLAM, SF ^{[1
]}

机构：

[1] UNIV NATAL,DEPT CHEM,MET CLUSTER CHEM UNIT,POB 375,PIETERMARITZBURG 3200,SOUTH AFRICA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 19期

关键词：

D O I：

10.1039/c39910001382

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Thermolysis of [Ru2(mu-CO)(CO)4{mu-(RO)2PN(Et)P(OR)2}2] or [Ru2H2(CO)4{mu-(RO)2PN(Et)P(OR)2}2] (R = Me or Pr(i)) under appropriate reaction conditions affords the formally unsaturated species [Ru2(CO)4{mu-(RO)2PN(Et)P(OR)2}2], which reacts spontaneously at room temperature with various substrates; the crystal structure of [Ru2(CO)4{mu-(Pr(i)O)2PN(Et)P(OPr(i))2}2] as well as that of [Ru2H2(CO)4{mu-(Pr(i)O)2PN(Et)P(OPr(i))2}2] is reported.

引用

页码：1382 / 1384

页数：3

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