IMIDAZOLE BUFFER-CATALYZED CLEAVAGE AND ISOMERIZATION-REACTIONS OF DINUCLEOTIDES - THE PROPOSED MECHANISM IS INCOMPATIBLE WITH THE KINETIC MEASUREMENTS

被引：20

作者：

HAIM, A

机构：

[1] Department of Chemistry, State University of New York, New York 11794, Stony Brook

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1992年 / 114卷 / 22期

关键词：

D O I：

10.1021/ja00048a006

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

It is shown that the mechanism and the kinetic model proposed for the imidazole-catalyzed cleavage and isomerization reactions of dinucleotides (Breslow, R.; Huang, D.- L, J. Am. Chem. Soc. 1990, 112, 9621. Anslyn, E.; Breslow, R. J. Am. Chem. Soc. 1989, 111, 4473) are incompatible with the kinetic measurements.

引用

页码：8384 / 8388

页数：5

共 12 条

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