AL-27 NMR-STUDIES OF ALUMINIUMPORPHYRINS

被引：5

作者：

DESIMONE, JM

STANGLE, M

RIFFLE, JS

MCGRATH, JE

机构：

[1] VIRGINIA POLYTECH INST & STATE UNIV,NAT SCI FDN,BLACKSBURG,VA 24061

[2] VIRGINIA POLYTECH INST & STATE UNIV,DEPT CHEM,BLACKSBURG,VA 24061

来源：

MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA | 1991年 / 42-3卷

关键词：

D O I：

10.1002/masy.19910420131

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Aluminium-27 NMR has been employed to study several different aluminiumporphyrins based on (5, 10, 15, 20-tetraphenyl)porphyrin (TPPH2). The aluminium porphyrins were formed by reacting a stoichiometric amount of trialkylaluminium with TPPH2 to yield TPPA1-R. The resulting aluminiumporphyrin was modified by adding a stoichiometric amount of various carboxylic acids to form aluminiumporphyrin carboxylates that had varying steric and electronic effects on the macrocycle.

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页码：373 / 385

页数：13

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