ALPHA-D-MANNOSYL AND BETA-D-GALACTOSYL DERIVATIVES OF CYCLODEXTRINS

被引：19

作者：

LANCELONPIN, C

DRIGUEZ, H

机构：

[1] Centre de Recherches sur les Macromolécules Végétales, C.N.R.S., 38041 Grenoble Cedex

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 22期

关键词：

BRANCHED GALACTOSYL-CYCLODEXTRIN; BRANCHED MANNOSYL-CYCLODEXTRIN; BI-ANTENNARY GLYCOSYL-CYCLODEXTRIN;

D O I：

10.1016/S0040-4039(00)79830-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The syntheses of S-alpha-D-mannosyl- and S-beta-D-galactosyl-6-thio-cyclomaltoheptaoses have been achieved in high yield from 6-deoxy-6-iodo-CD and activated 1-thiosugars. "Cluster 1-thioglycosides" were also obtained by coupling these activated 1-thiosugars to 3-bromo-2-(bromomethyl)-propionic acid and then by attaching these bi-antennary structures to 6-amino-6-deoxy-CD through an amide linkage.

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页码：3125 / 3128

页数：4

相关论文

共 13 条

[1] ENZYMIC SYNTHESES OF DOUBLY BRANCHED CYCLOMALTOHEPTAOSES THROUGH THE REVERSE ACTION OF PSEUDOMONAS ISOAMYLASE [J].

ABE, J ;

HIZUKURI, S ;

KOIZUMI, K ;

KUBOTA, Y ;

UTAMURA, T .

CARBOHYDRATE RESEARCH, 1988, 176 (01) :87-95

[2] A CONVENIENT METHOD FOR S-GLYCOSIDIC BOND FORMATION - SYNTHESIS OF PARA-IODOPHENYL 4'-THIOMALTOTRIOSIDE AND ITS 2'',3''-UNSATURATED ANALOG [J].

BLANCMUESSER, M ;

DRIGUEZ, H .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1988, (12) :3345-3351

[3]

BODANSZKY M, 1988, PEPTIDE CHEM

[4]

COTTAZ S, 1989, SYNTHESIS-STUTTGART, P755

[5] BRANCHED THIOCYCLOMALTO-OLIGOSACCHARIDES - SYNTHESIS AND PROPERTIES OF 6-S-ALPHA-D-GLUCOPYRANOSYL-6-THIOCYCLOMALTOHEPTAOSE AND 6-S-BETA-D-GLUCOPYRANOSYL-6-THIOCYCLOMALTOHEPTAOSE .10. [J].

DEFAYE, J ;

GADELLE, A ;

GUILLER, A ;

DARCY, R ;

OSULLIVAN, T .

CARBOHYDRATE RESEARCH, 1989, 192 :251-258

[6] SYNTHESIS OF 6-O-ALPHA-D-GLUCOPYRANOSYLCYCLOMALTOHEPATOSE [J].

FUGEDI, P ;

NANASI, P ;

SZEJTLI, J .

CARBOHYDRATE RESEARCH, 1988, 175 (02) :173-181

[7] TARGETING OF NEOGLYCOPROTEIN-DRUG CONJUGATES TO CULTURED HUMAN EMBRYONAL CARCINOMA-CELLS [J].

GABIUS, HJ ;

BOKEMEYER, C ;

HELLMANN, T ;

SCHMOLL, HJ .

JOURNAL OF CANCER RESEARCH AND CLINICAL ONCOLOGY, 1987, 113 (02) :126-130

[8]

HUBER O, 1988, 4TH P INT S CYCL

[9]

LANCELON C, 1991, EUROCARB, V6

[10] BINDING CHARACTERISTICS OF N-ACETYLGLUCOSAMINE-SPECIFIC LECTIN OF THE ISOLATED CHICKEN HEPATOCYTES - SIMILARITIES TO MAMMALIAN HEPATIC GALACTOSE N-ACETYLGALACTOSAMINE-SPECIFIC LECTIN [J].

LEE, RT ;

RICE, KG ;

RAO, NBN ;

ICHIKAWA, Y ;

BARTHEL, T ;

PISKAREV, V ;

LEE, YC .

BIOCHEMISTRY, 1989, 28 (21) :8351-8358