SYNTHESIS OF A NEW KETONE AND ALCOHOL WITH C2 SYMMETRY - (S,S,S,S) TRICYCLO[6.3.0.0(3,7)]UNDECAN-2-ONE AND (S,S,S,S) TRICYCLO[6.3.0.0(3,7)]UNDECAN-2-OL

被引：7

作者：

MCINTOSH, JM

CASSIDY, KC

机构：

[1] Department of Chemistry, University of Windsor, Windsor

来源：

TETRAHEDRON-ASYMMETRY | 1991年 / 2卷 / 10期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1016/S0957-4166(00)86156-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Dissolving metal reduction of known enone 5 affords predominantly the racemic form of title ketone (3) whereas catalytic reduction gives the meso isomer 6. Neither ketone 3 nor alcohol 4 could be satisfactorily resolved. Asymmetric synthesis of (-)-3 and (+)-4 (ee = 91%) was effected from ketone (+)-13.

引用

页码：1053 / 1062

页数：10

共 34 条

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