HIGH-TEMPERATURE SYNTHESIS AND INVESTIGATION OF HEXAGONAL BORON CARBONITRIDE

被引：26

作者：

ANDREEV, YG ^{[1
]}

LUNDSTROM, T ^{[1
]}

机构：

[1] UNIV UPPSALA,INST CHEM,BOX 531,S-75121 UPPSALA,SWEDEN

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 1994年 / 210卷 / 1-2期

基金：

瑞典研究理事会;

关键词：

D O I：

10.1016/0925-8388(94)90155-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A set of boron carbonitride phases have been synthesized by nitration of boron carbide BC powder at 2100-degrees-C under various partial pressures of nitrogen. X-Ray diffraction and Raman spectroscopy studies establish graphite-like networks for the atomic arrangement within each of the ternary compounds formed. All B-C-N phases found are classified by a certain value of interplanar spacing, characteristic Raman band frequency and a degree of structural ordering. An increase of the synthesis temperature prevents the formation of ternary compounds in favour of graphite and hexagonal boron nitride.

引用

页码：311 / 317

页数：7

共 26 条

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