SYNTHESIS OF MODEL BLOCK COPOLYMERS OF POLY(CIS-1,4-ISOPRENE - STYRENE)

被引:20
作者
CRAMOND, DN
URWIN, JR
机构
[1] Department of Physical and Inorganic Chemistry, University of Adelaide, Adelaide, SA, 5001
关键词
D O I
10.1071/CH9681835
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The synthesis of model block copolymers of poly(cis-1, 4-isoprene: Styrene)initiated by butyllithium in the solvent benzene is described in detail, and the analysis of the microstructure of the polyisoprene sequence discussed. The copolymers were found to be of narrow distribution in molecular size and composition and the microstructure was close to that expected from previously published results on the synthesis of polyisoprenes. © 1968 CSIRO. All rights reserved.
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页码:1835 / &
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