A NEW RHODIUM(II) PHOSPHATE CATALYST FOR DIAZOCARBONYL REACTIONS INCLUDING ASYMMETRIC-SYNTHESIS

被引：123

作者：

MCCARTHY, N

MCKERVEY, MA

YE, T

MCCANN, M

MURPHY, E

DOYLE, MP

机构：

[1] QUEENS UNIV BELFAST,SCH CHEM,BELFAST BT9 5AG,NORTH IRELAND

[2] ST PATRICKS COLL,DEPT CHEM,MAYNOOTH,KILDARE,IRELAND

[3] TRINITY UNIV,DEPT CHEM,SAN ANTONIO,TX 78212

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 40期

关键词：

D O I：

10.1016/S0040-4039(00)61106-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new homochiral Rh(II) complex, Rh{HCO3}2{(+)-phos}2.5H2O, where (+)phosH represents (S)-(+)-1,1'-binaphthyl-2,2'-diyl hydrogen phosphate, has been prepared and used as a catalyst for reactions of diazocarbonyl compounds leading to enantioselective 2,3-sigmatropic rearrangement (first example), C-H insertion and aromatic cycloaddition

引用

页码：5983 / 5986

页数：4

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