THEORETICAL-STUDY OF HETEROATOM-CONTAINING COMPOUNDS - FROM AROMATIC AND POLYCYCLIC MOLECULES TO HOLLOW CAGE CLUSTERS

被引：55

作者：

NAGASE, S

机构：

[1] Department of Chemistry, Faculty of Education, Yokohama National University, Yokohama

来源：

PURE AND APPLIED CHEMISTRY | 1993年 / 65卷 / 04期

关键词：

D O I：

10.1351/pac199365040675

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By means of molecular orbital calculations, the compounds whose skeletons are made of the heavier group 14 or group 15 atoms are investigated. Included are the heavier analogues of aromatic, antiaromatic, and polycyclic carbon compounds. To characterize the properties of the heavier atom skeletons, the applicability of the important concepts such as aromaticity and strain established in carbon chemistry is discussed. It is found that substituents have remarkable effects on the aromaticity and strain of the heavier atom skeletons. Also investigated are the heavier analogues of hollow cage carbon clusters (fullerenes) of current interest.

引用

页码：675 / 682

页数：8

共 43 条

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