DENSITY-MATRIX DESCRIPTION OF LASER-INDUCED HOT-ELECTRON MEDIATED PHOTODESORPTION OF NO FROM PT(111)

被引：92

作者：

SAALFRANK, P

BAER, R

KOSLOFF, R

机构：

[1] HEBREW UNIV JERUSALEM, DEPT PHYS CHEM, IL-91904 JERUSALEM, ISRAEL

[2] HEBREW UNIV JERUSALEM, FRITZ HABER RES CTR MOLEC DYNAM, IL-91904 JERUSALEM, ISRAEL

来源：

CHEMICAL PHYSICS LETTERS | 1994年 / 230卷 / 4-5期

关键词：

D O I：

10.1016/0009-2614(94)01182-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Based on the numerical solution of the Liouville-von Neumann equation for dissipative systems, the photodesorption dynamics of NO/Pt(111) are studied. Dissipative terms are used to describe the quenching of electronically excited states on the metal, electronic dephasing and the indirect (hot-electron mediated) excitation processes in the DIMET and DIET limits. Norm and energy flow, desorption probabilities and density time-of-flight spectra are computed.

引用

页码：463 / 472

页数：10

共 25 条

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