H-1, C-13 AND SE-77 NMR-SPECTRA OF SUBSTITUTED SELENOANISOLES

被引：52

作者：

KALABIN, GA ^{[1
]}

KUSHNAREV, DF ^{[1
]}

BZESOVSKY, VM ^{[1
]}

TSCHMUTOVA, GA ^{[1
]}

机构：

[1] VI LENIN STATE UNIV,KAZAN,USSR

来源：

ORGANIC MAGNETIC RESONANCE | 1979年 / 12卷 / 10期

关键词：

D O I：

10.1002/mrc.1270121011

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The 1H, 13C and 77Se chemical shifts and the 1J[C(Me)H(Me)], 1.2J(SeC) and 2J(SeH) coupling constants in 14 para‐ or meta‐substituted selenoanisoles, RC6H4SeCH3, have been measured and the dependence of these parameters on the electronic effects of the substituent R is discussed. A significant (up to 6 ppm) deviation from additivity of the substituent influence on the shielding of the 13C ring carbons has been found. Copyright © 1979 Heyden & Son Ltd.

引用

页码：598 / 604

页数：7

共 41 条

[1] MOLECULAR POLARISABILITY . DIPOLE MOMENTS AND MOLAR KERR CONSTANTS OF SOME PARA-SUBSTITUTED ANISOLES [J].

ARONEY, MJ ;

LEFEVRE, RJW ;

PIERENS, RK ;

THE, MGN .

JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC, 1969, (06) :666-&

[2]

ARONEY MJ, 1971, J CHEM SOC B, P1182

[3] DIPOLE MOMENTS OF SOME ARYL METHYL SULPHIDES - EVIDENCE FOR EXPANSION OF VALENCE SHELL OF SULPHUR [J].

BALIAH, V ;

UMA, M .

TETRAHEDRON, 1963, 19 (03) :455-&

[4]

BATSANOV SS, 1962, ELEKTROOTRITSATELNOS, P65

[5] TERT-BUTYL GROUP AS SENSOR GROUP OF ORTHO-EFFECT [J].

BERGER, S .

TETRAHEDRON, 1976, 32 (20) :2451-2455

[6]

BLACKWELL LF, 1975, TETRAHEDRON LETT, P4271

[7] VALENCE SHELL CALCULATIONS ON POLYATOMIC MOLECULES .2. CNDO SCF CALCULATIONS ON MONOSUBSTITUTED BENZENES [J].

BLOOR, JE ;

BREEN, DL .

JOURNAL OF PHYSICAL CHEMISTRY, 1968, 72 (02) :716-&

[8]

BOROVIKOV YY, 1975, TEKH, V11, P108

[9] SUBSTITUENT EFFECTS ON C-13 NMR CHEMICAL-SHIFTS OF SIDE-CHAIN CARBONS IN AROMATIC SYSTEMS [J].

BROMILOW, J ;

BROWNLEE, RTC ;

CRAIK, DJ .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1977, 30 (02) :351-355

[10] C-13 NUCLEAR MAGNETIC-RESONANCE STUDIES OF ORTHO-SUBSTITUTED ANISOLES AND DIPHENYL ETHERS [J].

BUCHANAN, GW ;

MONTAUDO, G ;

FINOCCHI.P .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1974, 52 (05) :767-774

← 1 2 3 4 5 →